The spectrogram picture posted looks to me like a featureless carrier, the "features" look like Doppler shift in reflected energy from aircraft.
I am no expert, but at a guess the TDOA results are all over the place because there is no modulation. If there are indeed no features on the carrier, just a dead carrier, the Kiwi TDOA techniques, as I understand them, cannot be applied. So yeah, you can TDOA away, but the answers will be wrong, or at best a lucky guess.
T!