Thanks Token.
I measured pulse width on one of my recordings from last night - 62.5 it is, all depends of course where you place the start and end and with enough of wiggle you get 64

Perhaps the 1 PPS PIP signal we occasionally hear is not quite the 16ms I have been measuring.
I have seen you list of frequencies before and use it as a reference. When I find the PIPs active I search down to 2MHz and up over 10MHz but so far have not heard them below about 5MHz or above 9MHz - perhaps I just don't have the propagation at those times.
I have been searching the FCC database of experimental (and other) licencees that may have been assigned these frequencies but so far I haven't stumbled cross anything similar. The Canadian Industry Canada licence system is not as friendly but regardless I haven't noted anything similar. Of course it wouldn't be listed if it was military.
Indeed and interesting mystery.
cheers, Graham